It sounds like you may already have another copy of MultiChain running on the same computer. If you're using Linux can check this by using ps -x. In any event, the solution to this is to set a different port and/or rpcport on the command-line options, so the two nodes don't try to listen on the same TCP/IP ports. Or use the multichain.conf file to set these more permanently, in a way that multichain-cli can automatically read.