First, have you considered using a single transaction to cover both of the actions you wanted in separate transactions? There is a lot of flexibility in what can be done together using createrawsendfrom.
If this is not an option, first you need to ensure that this address has at least two unspent transaction outputs that it can use. You can do this by sending an amount to yourself. Then, when using createrawsendfrom for the first transaction, make sure you pass lock in the action parameter, so the second transaction doesn't try to spend the same output.